You have calibrated even if you do not realize it. You say you can cover one acre with 25 gal of mix. That is what calibration is. To reach this you have to travel at about the same speed each time and that is what calibration is, speed and distance to reach a goal. You know how much to cover an acre, half acre, or even a quarter acre. The only difference is your still having to figure how much chemical to add based on how much water besides just being able to dump in the amount of chemical you want to cover the area because you already know how much water is necessary. Hope this makes sense.
Now having said that, let’s look at your 2.5 oz per gallon mix rate. Each time you have to figure out how much chemical you will need to add based on how much water you use. Going by your numbers you are applying 62.5 oz of GLY on 1 acre. This is a hot dose which is close to 4 qt per acre rate (64 oz).
If your spraying once a year this is fine but if your making multiple applications a year you are going to reach the max application rate rather quickly and may not be able to make additional applications. We still have to be good stewards and make every attempt at keeping rates within allowable tolerances.
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