Depends a lot on the weather, your soil type, and organic matter content. Typically - everything average - i think the half life is three days. Half a dose (define the dose!) isn't enough to stop much of anything. The question was how long to wait to plant buckwheat? With a little bit of caution I'd say not at all. It's going to take 3-days to germinate, right? Or, spray, wait three days, plant and you'll be at least six days past any possible danger.