Crop oil could potentially damage the foliage of the brassicas and set them back, if it is a new flush young newly germinated grass, perhaps you could get away with a non-ionic surfactant such as dish soap, but I have never tried it on brassicas. I would think you would have to keep the crop oil rates low, see the clip below from the UMass website on growing vegetables:
Postemergence
clethodim (Select 2EC): 6 to 8 oz/A (20 dh, REI 24h, Group 1). Apply to actively growing grasses. See label for grass height and herbicide rate. Always use a crop oil concentrate at a rate of 1 gal/100 gal spray mix. See both container label and any supplemental label available from dealer.
Remember, ALWAYS read your herbicide labels from top to bottom before applying it to any crop.